Search results for "H control"
showing 10 items of 37 documents
Hybrid ferrocene ligands (P, N) : synthesis, coordination to metals and applications in arylation coupling catalysis
2017
The research theme developed during this thesis concerns the development of new hybrid ferrocene hybrid (P, N) ligands with controlled conformation, robust and stable to air. These hybrid tetradent ligands comprise two types of coordinating functions with distinct steric and electronic properties. Their coordination chemistry with metals such as gold or palladium has been studied and some isolated Au (I) complexes have been used in the arylation coupling catalysis of aryl iodides.
Development of Point-to-Point Path Control in Actuator Space for Hydraulic Knuckle Boom Crane
2020
This paper presents a novel method for point-to-point path control for a hydraulic knuckle boom crane. The developed path control algorithm differs from previous solutions by operating in the actuator space instead of the joint space or Cartesian space of the crane. By operating in actuator space, almost all the parameters and constraints of the system become either linear or constant, which greatly reduces the complexity of both the control algorithm and path generator. For a given starting point and endpoint, the motion for each actuator is minimized compared to other methods. This ensures that any change in direction of motion is avoided, thereby greatly minimizing fatigue, jerky motion,…
Solvent production from rice straw by a co-culture of Clostridium acetobutylicum and Saccharomyces cerevisiae: effect of pH control
2022
One of the challenges in biofuel production from lignocellulosic wastes is to improve its conversion to solvents; therefore, new strategies to enhance xylose uptake are required due to be the secondary abundant sugar. In this context, a novel fermentation strategy integrating a co-culture of Clostridium acetobutylicum and Saccharomyces cerevisiae with pH control was developed. Initially, two different buffers, ammonium acetate and calcium carbonate, were tested under pHmin > 4.8 by fermenting 60 g L−1 of glucose with the C. acetobutylicum monoculture. Ammonium acetate was selected for fermenting media as butanol production was increased from 9.8 to 10.9 g L−1 over the calcium carbonate test…
Application of a fuzzy algorithm for pH control in a struvite crystallisation reactor
2006
A struvite crystallisation process is highly dependent on pH. To achieve a high phosphorus recovery as struvite it is important to have an accurate control of pH in the reactor. The high non-linear response of pH value makes manual pH control difficult. Therefore, a software based on fuzzy logic control (FLC) has been developed to maintain the pH at a set value in a stirred reactor to crystallise struvite. The FLC developed has been based on Larsen's inference. In order to confirm the improvement of the pH stability using FLC software, different experiments have been carried out with manual control of the pH value, and with the FLC software. It has been demonstrated that using FLC software …
Delay-dependent control for 2-D switched delay systems in the second FM model
2013
This paper is concerned with the problem of delay-dependent H∞ control for 2-D (two-dimensional) switched discrete state delay systems described by the second FM (Fornasini and Marchesini) state-space model. Firstly, some sufficient conditions for the exponential stability and weighted H∞ disturbance attenuation performance of the underlying system are derived via the average dwell time approach. Then, based on the obtained results, a state feedback controller design is proposed to guarantee that the resulting closed-loop system is exponentially stable and achieves a prescribed disturbance attenuation level γ. Finally, a numerical example is provided to verify the effectiveness of the propo…
H∞ control for two-dimensional Markovian jump systems with state-delays and defective mode information
2013
This paper investigates the problem ofℋ∞state-feedback control for a class of two-dimensional (2D) discrete-time Markovian jump linear time-delay systems with defective mode information. The mathematical model of the 2D system is established based on the well-known Fornasini-Marchesini local state-space model, and the defective mode information simultaneously consists of the exactly known, partially unknown, and uncertain transition probabilities. By carefully analyzing the features of the transition probability matrices, together with the convexification of uncertain domains, a newℋ∞performance analysis criterion for the underlying system is firstly derived, and then theℋ∞state-feedback co…
Effects of electrical and mechanical parameters on the transient voltage stability of a fixed speed wind turbine
2011
Abstract In this paper the dynamic behaviour of a wind turbine connected to the grid is examined. The model of the fixed speed wind turbine has been developed with the Simulink simulation tool (Matlab Inc.) It is composed of the induction generator, the shaft system, an aerodynamic model of the wind turbine rotor and the pitch control system. Using this model, a three-phase fault is applied close to the wind turbine and cleared by disconnecting the faulty line. The rigorous implementation of the simulink model allowed the authors to evaluate the exact dependence of various electrical parameters for the induction generator on voltage stability. Furthermore, the effects of wind turbine mechan…
ChemInform Abstract: Preparation of N,O-Aminals as Synthetic Equivalents of H2C=NAr and (H2C=NHAr)+ Ions: Neutral- and Acid-Promoted Transformations.
1988
A general method for the synthesis of N,O-aminals derived from primary aromatic amines is described. The reactivity of these compounds under neutral and acidic conditions has been studied and the title compounds can be envisaged as general purpose H2CNAr or (H2CNHAr)+ equivalents. N,O-Aminals have been converted into perhydrotriazines by moderate heating and into bis(4-aminoaryl)methane derivatives or N-benzylarylamines, respectively when heated in acidic media with pH control. Reduction of N,O-acetals with sodium cyanoborohydride has revealed that the C–O bond is broken exclusively in acidic media.
A simulation and experimental study of electrochemical pH control at gold interdigitated electrode arrays
2021
Abstract In electroanalysis, solution pH is a critical parameter that often needs to be tailored and controlled for the detection of particular analytes. This is most commonly performed by the addition of chemicals, such as strong acids or bases. Electrochemical in-situ pH control offers the possibility for the local adjustment of pH at the point of detection, without the need for additional reagents. Finite element analysis (FEA) simulations have been performed on interdigitated electrodes, to guide experimental design in relation to both electroanalysis and in-situ control of solution pH. No previous model exists that describes the generation of protons at an interdigitated electrode arra…
Optimal design of an electro-hydraulic valve for heavy-duty vehicle clutch actuator with certain constraints
2016
Abstract The main objective of this paper is to investigate the sensitivity analysis and optimal design of a proportional solenoid valve (PSV) operated pressure reducing valve (PRV) for heavy-duty automatic transmission clutch actuators. The nonlinear electro-hydraulic valve model is developed based on fluid dynamics. In order to implement the sensitivity analysis and optimization for the PRV, the PSV model is validated by comparing the results with data obtained from a real test-bench. The sensitivity of the PSV pressure response with regard to the structural parameters is investigated by using Sobol׳s method. Finally, simulations and experimental investigations are performed on the optimi…